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Tamil KINETICS mechanism OF UNIMOLECULAR SURFACE CATALYSED REACTION Based on Langmuir adsorption isotherm, surface coverage θ derivation CASE 1 At low p, Kp less than 1, then (1+Kp) I order CASE 2 At high pressure p, Kp greater than 1 then (1+Kp) =Kpthen zero order. CASE 3 At intermediate p, it is non-linear and follows fractional order & eq. 1

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