Reversibility
A reversible process is one that proceeds slowly enough to remain in equilibrium throughout the process. For irreversible or non-equilibrium processes it is important to use the external pressure to calculate the PV work.

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PV Work (Examples)

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Enthalpy

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Adiabatic Irreversible Work.

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Path Functions

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Isochoric/Isovolumetric (Constant Volume) Process on P-V Diagram

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Entropy Changes

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Reversible, Isothermal Volume Changes

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